In situ synthesis of block copolymer nano-assemblies by polymerization-induced self-assembly under heterogeneous condition |
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Authors: | Sheng-li Chen Peng-fei Shi Wang-qing Zhang |
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Affiliation: | 1.Key Laboratory of Functional Polymer Materials of the Ministry of Education, Institute of Polymer Chemistry,Nankai University,Tianjin,China;2.Collaborative Innovation Center of Chemical Science and Engineering (Tianjin),Nankai University,Tianjin,China |
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Abstract: | Controlled synthesis of amphiphilic block copolymer nanoparticles in a convenient way is an important and interest topic in polymer science. In this review, three formulations of polymerization-induced self-assembly to in situ synthesize block copolymer nanoparticles are briefly introduced, which perform by reversible addition-fragmentation chain transfer (RAFT) polymerization under heterogeneous conditions, e.g., aqueous emulsion RAFT polymerization, dispersion RAFT polymerization and especially the recently proposed seeded RAFT polymerization. The latest developments in several selected areas on the synthesis of block copolymer nano-assemblies are highlighted. |
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