Synthesis of anionic methylpalladium complexes with phosphine-sulfonate ligands and their activities for olefin polymerization |
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| Authors: | Kochi Takuya Yoshimura Kenji Nozaki Kyoko |
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| Affiliation: | Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Tokyo 113-8656, Japan. nozaki@chembio.t.u-tokyo.ac.jp. |
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| Abstract: | Reaction of diarylphosphinobenzene-2-sulfonic acids with tertially amines, followed by addition of [PdMeCl(cod)], provided anionic methylpalladium(II) complexes with bidentate phosphine-sulfonate ligands, which show high activity for copolymerization of ethylene with methyl acrylate. |
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