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Gravitational field-flow fractionation in combination with flow injection analysis or electrothermal AAS for size based iron speciation of particles |
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| Authors: | Chantiwas R Beckett R Jakmunee J McKelvie I D Grudpan K |
| Institution: | a Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand b Water Studies Centre, Department of Chemistry, Monash University, Clayton, Vic. 3800, Australia |
| Abstract: | A simple gravitational field-flow fractionation (GrFFF) system was used for size separation of micron sized silica particles coated with hydrous iron oxide (geothite). The amount of iron on the particles was monitored either on-line by reverse-flow injection analysis (r-FIA) with chemiluminescence detection using luminol or off-line by electrothermal atomic absorption spectrophotometry (ETAAS). The combination of GrFFF with reverse FIA or with ETAAS has been demonstrated to be a cost-effective tool for size based iron speciation of particles. |
| Keywords: | Gravitational field-flow fractionation Flow injection analysis Field-flow fractionation Chemiluminescence Iron speciation Size based speciation |
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