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Highly porous and robust scandium-based metal-organic frameworks for hydrogen storage |
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| Authors: | Ibarra Ilich A Yang Sihai Lin Xiang Blake Alexander J Rizkallah Pierre J Nowell Harriott Allan David R Champness Neil R Hubberstey Peter Schröder Martin |
| Affiliation: | School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK. |
| Abstract: | The metal-organic frameworks NOTT-400 and NOTT-401, based on a binuclear [Sc(2)(μ(2)-OH)(O(2)CR)(4)] building block, have been synthesised and characterised; the desolvated framework NOTT-401a shows a BET surface area of 1514 m(2) g(-1) with a total H(2) uptake of 4.44 wt% at 77 K and 20 bar. |
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