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Continuous wave free precession: Practical analytical tool for low-resolution nuclear magnetic resonance measurements
Authors:R.B.V. Azeredo  L.A. Colnago  A.A. Souza
Affiliation:a Embrapa Instrumentação Agropecuária, Rua XV de Novembro 1452, São Carlos, SP 13560-970, Brazil
b Instituto de Qu?́mica de São Carlos, Universidade de São Paulo, Avenida do Trabalhador São-Carlense, 400, São Carlos, SP 13560-970, Brazil
c Departamento de F?́sica, Universidade Federal de Pernambuco, Recife, Pernambuco 50670-901, Brazil
Abstract:The use of continuous wave free precession (CWFP) as a practical analytical tool for quantitative determinations in low-resolution nuclear magnetic resonance (LRNMR) is examined. The requirements of this technique are shown to be no more demanding than those prevailing in free-induction decay or spin-echo measurements. It is shown that the substantial gain in signal to noise ratio for a given acquisition time permitted by CWFP, can be exploited with advantage in practically any application of LRNMR. This applies not only to homogeneous low viscosity liquid samples but also to multi-component systems where differences in relaxation times of each component permit a separation of the individual contributions. As an example, the use of CWFP for fast quantitative determination of oil and moisture in various seeds is presented.
Keywords:NMR   SSFP   CWFP   Oil analysis   Moisture analysis
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