| 柱撑阴离子粘土的合成、表征及催化性能研I.ZnAl─SiW11及ZnAl—SiW11Z的合成 |
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| 引用本文： | 胡长文,贺庆林,王恩波. 柱撑阴离子粘土的合成、表征及催化性能研I.ZnAl─SiW11及ZnAl—SiW11Z的合成[J]. 无机化学学报, 1995, 11(3): 327-330 |
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| 作者姓名： | 胡长文 贺庆林 王恩波 |
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| 作者单位： | 东北师范大学化学系, 长春130024,东北师范大学化学系, 长春130024,东北师范大学化学系, 长春130024 |
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| 基金项目： | 国家教委优秀青年教师基金;吉林大学无机水热合成开放研究实验室研究基金 |
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| 摘 要： | 采用水热合成及离子交换方法将缺位及单取代型Keggin结构钨硅杂多含氧酸根SiW11及SiW11O39Z(H2O)6-嵌入Zn─Al型阴离子粘土层间,得到了大层间距的新型层往状微孔材料ZnAl─SiW11及ZnAl-SiW11Z(Z=Co2+、Ni2+和Cu2+),XRD与IR测试结果表明,它们只有9.7Å 的通道高度.
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| 关 键 词： | 过渡元素 杂多含氧酸根 阴离子粘土 催化性能 |
| 收稿时间： | 1994-10-12 |
STUDY ON SYNTHESIS, CHARACTERIZATION AND CATALYSIS OF PILLARED ANION CLAY I. SYNTHESIS OF ZnAl-SiW11 AND ZnAl-SiW11Z |
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| Hu Changwen,He Qinglin and Wang Enbo. STUDY ON SYNTHESIS, CHARACTERIZATION AND CATALYSIS OF PILLARED ANION CLAY I. SYNTHESIS OF ZnAl-SiW11 AND ZnAl-SiW11Z[J]. Chinese Journal of Inorganic Chemistry, 1995, 11(3): 327-330 |
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| Authors: | Hu Changwen He Qinglin Wang Enbo |
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| Affiliation: | Department of Chemistry, Northeast Normal University, Changchun 130024,Department of Chemistry, Northeast Normal University, Changchun 130024 and Department of Chemistry, Northeast Normal University, Changchun 130024 |
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| Abstract: | Layered double hydrotalcites pillared by heteropolyoxometates,ZnAl-SiW11 and ZnAl-SiW11Z(Z=Co2+,Ni2+and Cu2+)have been synthesized via both hydrothcrmal reaction and anion exchange. A procedure for intcrcalation layered double hydroxidcs is described:powder X-ray diffraction,IR and thermogravimmctric mcasurcmcnts confirm that for SiW11 and SiW11Z intcrcalation takes place and results in gallery heights of 9.7Å. |
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| Keywords: | transition element heteropolyoxometate anionclay synthesis |
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