Enthalpies of interaction of urea in mixtures of water and N,N-dimethylformamide at 25°C |
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Authors: | André H. Sijpkes Gus Somsen |
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Affiliation: | (1) Department of Chemistry and Biochemistry, University of Colorado at Boulder, Campus Box 215, 80309-0215 Boulder, CO, U.S.A.;(2) Faculteit der Scheikunde, Vakgroep Fysische en Theoretische Chemie, Vrije Universiteit, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands |
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Abstract: | Enthalpies of dilution of urea dissolved in mixtures of water and N,N-dimethylformamide with mole fractions of water 0.33, 0.50 and 0.67, respectively, have been measured calorimetrically at 25°C. From these, enthalpic interaction coefficients were obtained. The present results are compared with those of urea dissolved in pure water and in pure N,N-dimethylformamide. |
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Keywords: | Enthalpy of interaction urea mixtures of water and N,N-dimethylformamide |
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