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Optoelectronic characteristics of >9% efficient bilayered CuZnSn(S,Se)4 photovoltaic device
Authors:Wei Wu  Nancy G. Tassi  Yanyan Cao  Jonathan V. Caspar  Kaushik Roy‐Choudhury  Lei Zhang
Affiliation:DuPont Central Research and Development, Wilmington, USA
Abstract:Using binary and ternary chalcogenide nanoparticle solutions as precursors, a bi‐layered CZTSSe film is formed after being annealed in selenium atmosphere. Based on the CZTSSe film, a high efficiency thin‐film photovoltaic device (9.02% conversion efficiency) is made. Detailed characterizations of the device's performance and composition from XPS depth profiling are presented, and based on the results we discuss possible areas for further efficiency improvement. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)
Keywords:CuZnSn(S,Se)4  photovoltaics  solution processing  thin films  solar cells
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