| 水溶性铑膦配合物催化烯烃氢甲酰化反应研究进展 |
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| 引用本文： | 付海燕,袁茂林,陈华,李瑞祥,李贤均.水溶性铑膦配合物催化烯烃氢甲酰化反应研究进展[J].催化学报,2010,31(3):251-260. |
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| 作者姓名： | 付海燕 袁茂林 陈华 李瑞祥 李贤均 |
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| 作者单位： | 四川大学化学学院绿色化学与技术教育部重点实验室,四川成都,610064 |
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| 基金项目： | 国家自然科学基金(29792074) |
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| 摘 要： | 水/有机两相体系中水溶性铑膦配合物催化的烯烃氢甲酰化反应由于具有环境友好和催化剂容易分离等优点而受到广泛关注. 其中水溶性催化剂体系已经用于丙烯氢甲酰化反应制备丁醛的工业化生产. 然而, 长链烯烃在含有催化剂的水相中溶解性较差, 反应速率较慢. 综述了有关加速水/有机两相体系中长链烯烃氢甲酰化反应的方法和进展, 包括使用具有表面活性的膦配体, 以及在催化体系中添加环糊精和表面活性剂等促进剂. 另外, 还讨论了有关内烯烃氢甲酰化反应和提高直链醛选择性的方法.
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| 关 键 词： | 水溶性铑配合物 膦配体 烯烃 氢甲酰化 |
| 收稿时间： | 2010-03-25 |
Progress of Olefin Hydroformylation Catalyzed by Water-Soluble Rho-dium-Phosphine Complexes |
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| FU Haiyan,YUAN Maolin,CHEN Hua,LI Ruixiang,LI Xianjun.Progress of Olefin Hydroformylation Catalyzed by Water-Soluble Rho-dium-Phosphine Complexes[J].Chinese Journal of Catalysis,2010,31(3):251-260. |
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| Authors: | FU Haiyan YUAN Maolin CHEN Hua LI Ruixiang LI Xianjun |
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| Institution: | Key Laboratory of Green Chemistry and Technology of Ministry of Education, Department of Chemistry, Sichuan University, Chengdu 610064, Sichuan, China |
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| Abstract: | Olefin hydroformylation catalyzed by water-soluble rhodium-phosphine complexes in aqueous/organic biphasic systems is very popular for its remarkable advantages such as environmentally friendly nature and easy catalyst separation. Some aqueous catalysis systems have been applied in the industrial production of butyl aldehyde by propene hydroformylation. However, for long-chain olefins, the reaction is retarded for their poor solubility in the aqueous phase containing catalysts. The strategy and the progress... |
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| Keywords: | water-soluble rhodium complex phosphine ligand olefin hydroformylation |
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