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Dynamic charges for photoexcited defects in trans (CH)x
Authors:E.J. Mele
Affiliation:Department of Physics, University of Pennsylvania, PA 19104-3859, U.S.A.
Abstract:We show that the dynamic charge for an arbitrary vibrational excitation of a photogenerated defect in (CH)x vanishes in the SSH Hamiltonian for a band filling which is symmetric with respect to the interchange of electrons and holes. As a consequence solitonic excitons do not contribute to the infrared conductivity although dissociated charged defects do. Trapping of dissociated kinks at defects on the chain is suggested as a pinning mechanism.
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