Spin autocorrelation of Ni in K2Mn0.975Ni0.025F4 studied by nuclear spin-lattice relaxation

From the nuclear spin-lattice relaxation of the out-of-layer ¹⁹F nuclei in magnetic fields perpendicular to the c-axis the low-frequency component of the autocorrelation function 〈S^z(t)S^z(O)〉 of Ni in ordered K₂Mn_0.975Ni_0.025F₄ is found to be substantially reduced relative to the Mn host. The experimental rates vs temperature are in accord with those for relaxation involving two spin excitations calculated with local Green's functions.