Ethylene oligomerization on heterogenized titanium and zirconium complexes |
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| Authors: | H. Fuhrmann V. A. Semikolenov Yu I. Yermakov |
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| Affiliation: | (1) Central Institute of Organic Chemistry, Department of Complex Catalysis, Acad. Sci. GDR, Rostock, GDR;(2) Institute of Catalysis, Sibirian Branch of the USSR Acad. Sci., Novosibirsk, USSR |
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| Abstract: | Besides other products, linear middle-range olefins were obtained in the low temperature oligomerization of ethylene with a selectivity of 30–58% and a linearity up to 85%. Activated ticanium and zirconium complexes as catalysts were attached to SiO2 through surface bounded bidentate S- and N-containing ligands, the former being superior to the latter with respect to product quality.
                             30–58 .% 85%.  - -  , , SiO2  S- N- .  , , .
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