Mechanism of action of sulfur-containing complexes in oxidation processes |
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| Authors: | N M Emanuel Z K Maizus and V G Vinogradova |
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| Institution: | (1) Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow |
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| Abstract: | A mechanism of the inhibiting action of Cu(II), Ni(II), Pb(II), Zn bis(N, N-dialkyldithiocarbamates) and Cu(II) bis ( -thiopicolineanilides) in the AIBN initiated oxidation of ethylbenzene, styrene and nonene-1 is proposed. Inhibition is due to the deactivation of free radicals upon interaction with the chelate active center consisting of a metal with coordinated ligand atoms. As supported by the experimental data, the reaction occurs by an electron transfer mechanism.
                       -(N,N- ) Cu(II), Ni(II), Pb(II), Zn -(- ) Cu(II)       , -1.  .  .  .
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