Influence of secondary chemical reactions on the selectivity of the multiphoton dissociation process in C6F5H?C6F5D mixtures |
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| Authors: | V V Vizhin A K Petrov S I Turyev and A B Baklanov |
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| Institution: | (1) Institute of Chemical Kinetics and Combustion, Novosibirsk, USSR |
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| Abstract: | Radical acceptors significantly increasing the dissociation selectivity in C6F5H–C6F5D mixtures have been selected by studying the mechanism of C6F5H dissociation in the field of a pulsed CO2-laser. The contribution of secondary chemical reactions to the total rate of consumption of the initial molecules has been determined.
                C6F5H     CO2-     ,   C6F5H C6F5D.   .
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