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金属纳米粒子/聚合物体系的稳定性及其机理
引用本文:杨强,王立,向卫东,王驰亮,周峻峰. 金属纳米粒子/聚合物体系的稳定性及其机理[J]. 化学进展, 2006, 18(2): 290-297
作者姓名:杨强  王立  向卫东  王驰亮  周峻峰
作者单位:浙江大学聚合反应工程国家重点实验室,杭州,310027;温州大学应用技术学院,温州,325035
摘    要:金属纳米粒子由于其小的尺寸和大的比表面积等特点,使其具有独特的热性能、电性能、磁性能和光性能,以及很强的团聚趋势。因此金属纳米粒子是否被稳定在纳米尺度内,是它们能否表现出独特性能的关键。本文综述了非离子聚合物、聚电解质、两亲聚合物、双亲水聚合物、树状聚合物对金属纳米粒子的稳定作用及其稳定机理的研究进展。

关 键 词:金属纳米粒子  团聚  非离子聚合物  聚电解质  两亲聚合物  双亲水聚合物  树状聚合物  稳定机理
文章编号:1005-281X(2006)02/3-0290-08
收稿时间:2005-01-01
修稿时间:2005-05-01

Stabilization and Its Mechanisms of the Metal Nanoparticles/Polymer Systems
Yang Qiang,Wang Li,Xiang Weidong,Wang Chiliang,Zhou Junfeng. Stabilization and Its Mechanisms of the Metal Nanoparticles/Polymer Systems[J]. Progress in Chemistry, 2006, 18(2): 290-297
Authors:Yang Qiang  Wang Li  Xiang Weidong  Wang Chiliang  Zhou Junfeng
Affiliation:1. State Key Laboratory of Polymer Reaction Engineering, Zhejiang University, Hangzhou 310027, China; 2. College of Application and Technology, Wenzhou University, Wenzhou 325035, China
Abstract:Metal nanoparticles exhibit unique thermal, electronic, magnetic and optical properties because of the small sizes, large specific surface characteristics and the aggregative trend. Whether metal nanoparticles can be stabilized in nano scale is the key for them to exhibit unique properties. The progress in stabilizations and stabilization mechanisms of the metal nanoparticles by nonionic polymers, polyelectrolytes, amphiphilic polymers, double-hydrophilic polymers, and dendrimers is reviewed.
Keywords:metal nanoparticles   aggregation   nonionic polymers    polyelectrolytes   amphiphilic polymers double-hydrophilic polymers    dendrimers   stabilization mechanisms
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