Enantiospecific synthesis of angular triquinanes |
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Authors: | Adusumilli Srikrishna Vijayendran Gowri |
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Affiliation: | Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India |
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Abstract: | The enantiospecific synthesis of angular triquinanes has been developed starting from the readily available (S)-campholenaldehyde. Two alternate strategies have been used, one employing a Johnson’s orthoester Claisen rearrangement followed by an intramolecular cyclopropanation and regioselective cyclopropane ring cleavage, and a second one based on a RCM reaction. |
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