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Molecular structure of di-tert-butylamine-containing the monoedge-functionalized clathrochelate iron(II) tris-dioximate
Authors:A. B. Burdukov  N. V. Pervukhina  M. A. Vershinin  Ya. Z. Voloshin
Affiliation:(1) A. V. Nikolaev Insitute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow
Abstract:The structure of 1,8-bis(fluoroboro)-2,7,9,14,15,20-hexaoxa-3,6,10,13,16,19-hexaaza-4,5,11,12-tetraphenyl-17,18-bisc(tert-butylamino)-bicyclo[6.6.6]eicosa-3,5,10,12,16,18-hexaene(2?)iron(2+) tris-dioximate clathrochelate was determined by X-ray diffraction (XRD) analysis. The compound has a molecular structure and crystallizes as triclinic crystals: a = 10.7673(2) Å, b = 11.9520(4) Å, c = 22.5473(7) Å, α = 75.729(1)°, β = 89.161(1)°, γ = 65.334(1)°, V = 2542.64(13) Å3, Z = 2, space group 1. P1¯.
Keywords:clathrochelates  iron(II)  structures
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