Thermal studies on copper(II)-5,5′-thiodisalicylic acid complexes |
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Authors: | P C Srivastava S K Adhya |
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Institution: | (1) Physical Research Wing, Fertilizer (P & D) India Limited, 828122 Sindri, India |
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Abstract: | Aquo, ammonia and pyridine complexes of copper(II) with 5,5 -thiodisalicylic acid have been investigated by TG and DTG. All these complexes decompose in three distinct steps, viz. dehydration, loss of axial bases and decarboxylation of the aromatic ligand. The thermal curves of the aquo and pyridine complexes show water loss in two distinct steps. The decreasing order of thermal stability of the complexes is py > NH3 > H2O.
Zusammenfassung Aquo-, Ammoniak- und Pyridinkomplexe von Kupfer(II) mit 5,5 -Thiodisalicylsäure wurden durch TG und DTG untersucht. Diese Komplexe werden in den drei Stufen, Dehydratisierung, Verlust axialer Basen und Decarboxylierung des aromatischen Liganden zersetzt. Die Abbaukurven der Aquo- und Pyridinkomplexe zeigen einen Wasserverlust in zwei Stufen. Die abnehmende Reihenfolge der Thermostabilität der Komplexe ist py > NH3 > H2O.
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