1. N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, RUSSIA;2. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 117813 Moscow, RUSSIA
Abstract:
Reaction of 6‐acetyl‐7‐aminofurazano3,4‐b]pyridines with DMFDMA afforded N,N‐dimethylformamidines that were cyclized to the novel furazan‐fused 1,6]naphthyridine system by treatment with sodium methylate in good yield. The tricyclic system is characterized by X‐ray crystallography.