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Poly(N‐Bromobenzene‐1,3‐Disulfonylamide), N,N,N′,N′‐Tetrabromobenzene‐1,3‐Disulfonylamide and DABCO‐Bromine Complex: As Novel Reagents for the Oxidative Coupling of Thiols to Disulfides
Authors:Ramin Ghorbani‐Vaghei  Mohammad Ali Zolfigol  Nasrin Moshfeghifar  Nadiya Koukabi  Gholamabbas Chehardoli
Institution:Faculty of Chemistry, Bu‐Ali Sina University, Hamadan, Iran
Abstract:An efficient method for the oxidative coupling of thiols to their corresponding disulfides by new reagents poly(N‐bromobenzene‐1,3‐disulfonylamide) PBBS , N,N,N′,N′‐tetrabromobenzene‐1,3‐disulfonylamide TBBDA and DABCO‐bromine complex is described. The reaction was applicable to a variety of thiols with high chemoselectivity.
Keywords:Oxidation  Thiols  Mercaptans  Disulfides  Oxidative coupling of thiols  PBBS  TBBDA  DABCO‐bromine complex
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