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BIFC and QFC promoted rapid and cleaner aromatization of 1,4‐dihydropyridines under solvent‐free condition
Authors:Vajiravelu Sivamurugan  Velayutham Murugesan  Valiyaveettil Suresh  Muthaiyahpillai Palanichamy  Ajayan Vinu
Institution:1. Department of Chemistry, Anna University, Sardar Patel Road, Chennai 600025, India;2. Department of Chemistry, National University of Singapore, 3 Science drive 3, 117 543, Singapore;3. ICYS Fellow, National Institute for Materials Science, 1‐2‐1, Tsukuba, Ibaraki305 0047, Japan
Abstract: chemical structure image This communication expresses aromatisation of 1,4‐dihydropyridines to pyridine derivatives with the help of alumina supported benzimidazolium fluorochromate (BIFC) and quinolinium fluorochromate (QFC) as oxidants under solvent‐free microwave irradiation. Moderate to excellent yield (80‐98%) of pyridine derivatives were achieved by this methodology.
Keywords:
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