The First Metal‐Carbon Bond β‐Isomer Paddlewheel Pd24+ Compounds |
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| Authors: | Kuang‐Hway Yih Gene‐Hsiang Lee |
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| Affiliation: | 1. Department of Applied Cosmetology, Hungkuang University, Shalu, Taichung 433, Taiwan, R.O.C.;2. Instrumentation Center, College of Science, National Taiwan University, Taiwan, R.O.C. |
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| Abstract: | The first metal‐carbon bond β‐form paddlewheel complexes containing a Pd24+ core, [Pd(η2‐dithio)]2(μ‐dppa)( μ‐SCNMe2) (dithio = S2P(OEt)2, 2 ; S2COEt, 3 ; S2CNC4H8, 4 ), were prepared by the reactions of the α‐form paddlewheel‐type Pd2+4 dipalladium complex [Pd2 (μ‐Hdppa)2(μ‐SCNMe2)2][Cl]2, 1 with various dithio‐ligands, [NH4][S2P(OEt)2], [K][S2COEt] and [NH4][S2CNC4H8], in methanol at ambient temperature (Hdppa = bis(diphenylphosphino)amine). Electronic spectra and two X‐ray structures of the Pd2+4 species have been determined. |
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| Keywords: | Metal‐carbon bond β ‐Isomer Paddlewheel type Dipalladinum X‐ray structures |
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