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Total Synthesis of (±)‐Boonein |
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| Authors: | Meng‐Yang Chang Chun‐Yu Lin Pei‐Pei Sun Nein‐Chen Chang |
| Affiliation: | 1. Department of Applied Chemistry, National University of Kaohsiung, Kaohsiung 811, Taiwan, R.O.C.;2. Department of Chemistry, National Sun Yat‐Sen University, Kaohsiung 804, Taiwan, R.O.C.;3. Center of General Studies, National Kaohsiung Marine University, Kaohsiung 811, Taiwan, R.O.C. |
| Abstract: | A total synthesis of (±)‐boonein ( 8 ) from bicyclo[2.2.1]ketone 9 is described. Bicyclo[3.2.1]lactone 10 is the key intermediate. |
| Keywords: | Boonein 7‐Oxo‐boonein Baeyer‐Villiger lactonization Bicyclo[2.2.1]ketone Bicyclo[3.2.1]lactone Mitsunobu reaction |