BF3‐Oet2/Et3SiH‐Mediated Rearrangement of 4‐Aryl‐5,5‐Diphenylazapan‐4‐Ols |
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| Authors: | Meng‐Yang Chang Yung‐Hua Kung Shui‐Tein Chen |
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| Institution: | 1. Department of Applied Chemistry, National University of Kaohsiung, Kaohsiung 811, Taiwan, R.O.C.;2. Institute of Biological Chemistry, Academia Sinica, Nankang, Taipei 115, Taiwan, R.O.C. |
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| Abstract: | Synthesis of 2‐(2‐arylethyl)‐3,3‐diphenylpyrrolidines has been established starting from different 4‐aryl‐5,5‐diphenylazepan‐4‐ols via boron trifluoride etherate/triethylsilane‐mediated rearrangement. |
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| Keywords: | Rearrangement Boron trifluoride etherate Triethylsilane 2‐(2‐Arylethyl)‐3 3‐diphenylpyrrolidine 3 3‐Diphenylazepan‐4‐one |
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