| 苯甲醛缩三乙烯四胺Schiff碱Co(Ⅱ)配合物固相合成及氧合性能研究 |
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| 引用本文： | 肖芙蓉,王吉德,岳凡,武荣兰,陈鹭. 苯甲醛缩三乙烯四胺Schiff碱Co(Ⅱ)配合物固相合成及氧合性能研究[J]. 无机化学学报, 2006, 22(7): 1293-1298 |
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| 作者姓名： | 肖芙蓉 王吉德 岳凡 武荣兰 陈鹭 |
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| 作者单位： | 1. 新疆大学化学化工学院,乌鲁木齐,830046;石河子大学化学化工学院,石河子,832000
2. 新疆大学化学化工学院,乌鲁木齐,830046 |
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| 基金项目： | 国家高技术研究发展计划(863计划);新世纪优秀人才支持计划;广东省博士启动基金 |
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| 摘 要： | Three new cobalt complexes were synthesized by solid-state reaction at room temperature. It was found that one mole of complex reacted with two moles of oxygen at room temperature. And the oxygenated complexes [Co·(L1)2·2O2](NO3)2·2H2O (L1=N,N′-bis(4-hydroxyl-3-methoxy-benzyl)-triethylenetetramine), [Co·(L2)2·2O2](NO3)2 ·2H2O (L2=N,N′-bis(4-hydroxyl-benzyl)-triethylenetetramine) and [Co·L3·2O2](NO3)2·2H2O (L3=N,N′-bis(2-hydroxyl-benzyl)-triethylenetetramine) were obtained and characterized by elemental analysis, IR spectra, 1H NMR, TG/DTA, UV-Vis and molar conductance. The coordinated oxygen contents in the oxygenated complex were also determined by weight method. It was found that one O2 molecule coordinated to the Co ion and formed superoxo type oxygenated complex.
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| 关 键 词： | Schiff碱； 氧载体； 固相反应； 氧合性能 |
| 文章编号： | 1001-4861(2006)07-1293-06 |
| 收稿时间： | 2005-12-19 |
| 修稿时间： | 2006-04-25 |
Studies on Solid State Synthesis and Oxygenation Property of Cobalt(Ⅱ) Schiff Base(benzaldehyde triethylenetetramine) Complexes |
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| XIAO Fu-Rong,WANG Ji-De,YUE Fan,WU Rong-Lan and CHEN Lu. Studies on Solid State Synthesis and Oxygenation Property of Cobalt(Ⅱ) Schiff Base(benzaldehyde triethylenetetramine) Complexes[J]. Chinese Journal of Inorganic Chemistry, 2006, 22(7): 1293-1298 |
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| Authors: | XIAO Fu-Rong WANG Ji-De YUE Fan WU Rong-Lan CHEN Lu |
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| Affiliation: | School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046;School of Chemistry and Chemical Engineering, Shihezi University, Shihezi, Xinjiang 832000,School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046,School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046,School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046 and School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046 |
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| Abstract: | |
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| Keywords: | Schiff base oxygen carrier solid state reaction oxygenation property |
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