Electrochemically and photochemically active Palladium(II) heterotopic metallacalix[3]arenes |
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| Authors: | Galindo Miguel A Houlton Andrew Clegg William Harrington Ross W Dobado José Santoyo-Gonzalez Francisco Linares Fatima Romero M Angustias Navarro Jorge A R |
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| Affiliation: | Departamento de Química Inorgánica y Orgánica, Universidad de Granada, Av. Fuentenueva S/N, 18071, Granada, Spain. |
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| Abstract: | The cyclic trinuclear system, [(en)(3)Pd(3)(4,7-phen)(3)](6+), undergoes a ligand exchange reaction with 5-R-2-hydroxypyrimidine derivatives (HRpymo; R = ethynylferrocene, 5-(dimethylamino)-N-(2-propynyl)-1-naphthalene sulfonamide) to give [(en)(3)Pd(3)(4,7-phen)(2)(Rpymo)](5+), functional supramolecular receptors of mononucleotides. |
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