Metal-stabilized phenoxonium cation |
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| Authors: | Vigalok Arkadi Rybtchinski Boris Gozin Yael Koblenz Tehila S Ben-David Yehoshoa Rozenberg Haim Milstein David |
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| Affiliation: | Department of Organic Chemistry and Unit of Chemical Research Support, The Weizmann Institute of Science, Rehovot 76100, Israel. |
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| Abstract: | An unprecedented metal-stabilized phenoxonium cation was prepared by a process involving dearomatization of a phenoxy complex. The unique eta2 C=O-metal (iridium) coordination mode leaves the positive charge delocalized within the former aromatic ring. The X-ray structure and conversion into eta2 C=O-coordinated metal-quinone complex are described. |
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