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Development of a polystyrene sulfonate/silver nanocomposite with self-healing properties for biomaterial applications
Authors:Jérôme Girard  Priscilla S. Brunetto  Olivier Braissant  Zarko Rajacic  Nina Khanna  Regine Landmann  Alma U. Daniels  Katharina M. Fromm
Affiliation:1. Department of Chemistry, University of Fribourg, 9, chemin du Musée, 1700 Fribourg, Switzerland;2. Biomechanics & Calorimetry Center Basel/Pharmazentrum, University of Basel, Klingelbergstrasse 50-70, 4056 Basel, Switzerland;3. Infection Biology, Department of Biomedicine, University Hospital, 4056 Basel, Switzerland
Abstract:A silver polystyrene sulfonate polyelectrolyte was synthesized, showing a spontaneous reduction of silver ions to silver nanoparticles over a period of approximately 1 month. A follow-up of the nanoparticle formation via scanning electron microscopy (SEM) reveals migration of the nanoparticles towards the cracks of the polymer over time, leading to a self-healing process of the nanocomposite. Antibacterial tests show excellent antibacterial activity of our compound, which allows us to use this compound e.g. for external medical applications.
Keywords:Nanocomposite  Silver  Antibacterial  Self-healing  Biomaterial  Polymers
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