First nanoparticles of Bechgaard salts |
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| Authors: | Dominique de Caro Kane Jacob Christophe Faulmann Lydie Valade |
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| Affiliation: | 1. CNRS, Laboratoire de Chimie de Coordination (LCC), 205, route de Narbonne, BP 44099, 31077 Toulouse cedex 4, France;2. Université de Toulouse, UPS, INPT, 31077 Toulouse cedex 4, France |
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| Abstract: | Well-dispersed nanoparticles of the superconducting Bechgaard salts, namely (TMTSF)2PF6 and (TMTSF)2ClO4, have been electrochemically grown in organic solution in the presence of a supporting electrolyte either being an ionic liquid or a long alkyl-chains quaternary ammonium salt. Nanoparticles exhibit sizes in the 20–75 nm range. Nanoparticle powders have been characterized by infrared, Raman, visible absorption spectroscopy, and by preliminary transport measurements at room temperature. |
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| Keywords: | Nanoparticles Molecular superconductors Bechgaard salts Ionic liquids Long alkyl-chains quaternary ammonium salts Nanoparticules Supraconducteurs moléculaires Sels de Bechgaard Liquides ioniques sels d’ammonium quaternaires à longues chaînes alkyles |
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