Investigating the rate of photoreductive glucosyl radical generation |
| |
| Authors: | Andrews R Stephen Becker Jennifer J Gagné Michel R |
| |
| Institution: | University of North Carolina at Chapel Hill, Department of Chemistry, Chapel Hill, North Carolina 27599, United States. |
| |
| Abstract: | The photoreduction of glucosyl halides to generate glucosyl radicals has been investigated to probe the nature of the photoredox cycle. Amine (the reductant) and catalyst concentration affect the reaction rate at low concentrations but exhibit saturation at higher concentrations. Water and hydrophobic catalysts were found to significantly increase the conversion efficiency. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
