Terpyridine Metal Complexes as Building Blocks for Supramolecular Assemblies and Polymers: Thermal Stabilities and Thin Film Preparation |
| |
Authors: | Ulrich S Schubert Christian Eschbaumer Qingrui An Tim Salditt |
| |
Institution: | (1) Lehrstuhl für Makromolekulare Stoffe, Technische Universität München, Lichtenbergstr. 4, 85747 Garching, Germany;(2) Sektion Physik der Ludwig-Maximilians-Universität München, Geschwister-Scholl-Platz, 1, 80539 München |
| |
Abstract: | 5,5'-Dimethyl-2,2':6',2'-terpyridine complexes with various transition metal ions like Zn(II), Co(II), Mn(II) and Hg(II) were investigated concerning their thermal properties. A significant dependency of the thermal stability (5% weight loss) of the complexes depending on the kind of metal ion used could be observed ranging from 315 to 390 °C. Furthermore, self-assembled thin films of such metallo-supramolecular Hg(II) complexes were prepared and characterized by synchrotron based X-ray reflectivity and fluorescence techniques. |
| |
Keywords: | terpyridine metal complexes thermal stability thin film preparation supramolecular systems |
本文献已被 SpringerLink 等数据库收录! |
|