Efficient nickel/N-heterocyclic carbene catalyzed C-S cross-coupling |
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| Authors: | Pei GuanChangsheng Cao Yun LiuYunfei Li Pan HeQian Chen Gang LiuYanhui Shi |
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| Institution: | a School of Chemistry and Chemical Engineering and Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, Jiangsu 221116, PR China
b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, PR China |
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| Abstract: | The cross-coupling reaction of aryl halides with aliphatic and aromatic thiols catalyzed by readily available Ni(OAc)2 with N-heterocyclic carbene (NHC) is reported. Ni(OAc)2/NHC catalyst showed good activities toward various aryl halides in C-S coupling reaction, even with aryl chlorides. Reactions occurred in excellent yields, broad scope, and high tolerance of functional groups. |
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| Keywords: | C-S bond formation Cross-coupling Thiols Aryl halides |
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