PMR spectra of some five- and six-membered heterocyclic compounds of silicon and germanium

The PMR spectra of various 1-sila- and 1-germacyclopentanes and also those of some substituted disilacyclohexanes are discussed. The influence of the magnetic field of the aryl and vinyl substituents in 1,1-dialkyl-2,5-diaryl(vinyl)-1-sila(germa)cyclopentanes on the chemical shifts of the protons of the individual groups is studied, the differences found in the position of the PMR lines of the methyl and methylene groups showing the existence of cis-trans isomers in these heterocycles. With 1,1-dimethyl-2,5-divinylsilacyclopentane as an example, an increase in screening due to the magnetism of the multiple bonds for the protons of groups not directly connected with the unsaturated groupings and located in a direction perpendicular to the axis of the double bond has been found experimentally.Lecture at the XI-th Scientific Conference of the Institute of High-Molecular-Weight Compounds of the Academy of Sciences of the USSR (Leningrad, March, 1964) and at the All-Union Conference on the Use of Radiospectroscopy in Chemistry (Moscow, January, 1965).The authors express their gratitude to A. V. Kessenikh for taking several of the PMR spectra and for critical observations on the investigation.