Beiträge zur Chemie des Sulfamids, 1. Mitt.: Zur Konstitution des Disilber-sulfamids |
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| Authors: | Prof. Dr. E. Nachbaur A. Popitsch P. Burkert |
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| Affiliation: | 1. Institut für Anorganische und Analytische Chemie der Universit?t Graz, Universit?tsplatz 1, A-8010, Graz, ?sterreich
2. Anorganisch-chemisches Laboratorium der technischen Universit?t, München, BRD
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| Abstract: | According to spectroscopic (IR, broadline proton NMR) and chemical (alkylation) investigations of disilver sulphamide the following molecular structure is assumed: $$begin{gathered} O hfill || hfill H_2 N__S__NAg| hfill OAg hfill end{gathered}$$ From the IR and NMR data deduction concerning the nature of the chemical bonds in this compound is possible. The instability of the still unknown mono-and trisilver sulphamide is discussed with regard to the structure of disilver sulphamide. |
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