Rhodium-complex-catalyzed addition reactions of chloroacetyl chlorides to alkynes |
| |
| Authors: | Kashiwabara Taigo Fuse Kouichiro Hua Ruimao Tanaka Masato |
| |
| Institution: | Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan. |
| |
| Abstract: | The addition reaction of chloroacetyl chloride derivatives with terminal alkynes was found to be catalyzed by Rh(acac)(CO)(AsPh(3)) to afford (Z)-1,4-dichloro-3-buten-2-one derivatives, which displayed diverse reactivities in synthetic elaboration. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
