Fragmentation of 1-hydroxy-2-(5H-dibenzo[a,d]cyclohepten-5-yl)-1-phenylethyl cation in superacid |
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| Authors: | S. A. Osadchii M. D. Stanescu V. I. Mamatyuk V. G. Shuhin |
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| Affiliation: | (1) Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 7 prosp. Akad. Lavrent'eva, 630090 Novosibirsk, Russia;(2) Department of Organic Chemistry, Bucharest Polytechnic Institute, 76206 Bucharest, Romania |
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| Abstract: | The 1-hydroxy-2-(5H-dibenzo[a,d]cyclohepten-5-yl)-1-phenylethyl cation generated under  long life conditions undergoes fragmentation to afford 5H-dibenzo[a,d]cycloheptenyl-and methylphenylhydroxycarbinyl canons but does not undergo carbocationic cyclization.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 397–399, February, 1996. |
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| Keywords: | ethyl cation 5H-dibenzo[a,d]cycloheptene 5H-dibenzo[a,d]cycloheptenylium cation fragmentation superacid |
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