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A fast photometric titration for the standardization of dithizone solutions
Authors:S Alegret  M Blanco  JM Paulís
Institution:Department de Quiímica Analítica, Universitat Autònoma de Barcelona, Bellaterra, Barcelona Spain
Abstract:A simple method is reported for standardizing 10?5–10?4 M dithizone solutions for titrimetric analysis. Dithizone in an anhydrous acetic acid/chloroform (4% v/v) medium is titrated with 2 × 10?4 M mercury(II) acetate in the same medium. The titratioin takes only a few minutes. The accuracy (+0.2%) and precision (r.s.d. = 0.7%) achieved are similar to those obtained by the classical extractive titration with silver(I).
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