Preconcentration and x-ray spectrometric determination of arsenic(III/V) and chromium(III/VI) in water |
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Authors: | D.E. Leyden K. Goldbach A.T. Ellis |
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Abstract: | The speciation of chromium and arsenic in their two common oxidation states is determined by the use of selective preconcentration and energy-dispersive x-ray spectrometry. Chromium(VI) and arsenic(III) are recovered by precipitation with dibenzyldithiocarbamate and filtration. Chromium(III) and arsenic(V) are determined in the filtrate by coprecipitation with hydrated iron(III) oxide. The chromium and arsenic content of each precipitate is determined by use of x-ray spectrometry. |
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