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meso-四(2-羟基-5-磺酸苯基)卟啉的合成及其酸碱平衡的研究
引用本文:陈秀华,汤福隆,杨雪梅. meso-四(2-羟基-5-磺酸苯基)卟啉的合成及其酸碱平衡的研究[J]. 分析化学, 1991, 19(4): 427-429
作者姓名:陈秀华  汤福隆  杨雪梅
作者单位:杭州大学化学系 杭州310028
摘    要:本文对 meso-四(2-H-5-SP)P 的提纯方法进行了改进,同时以光度法研究了该试剂在水溶液中的酸碱平衡、测得其 pKa_1、pKa_2、pKa_3、pKa_4分别为2.99,4.21,8.68,10.28。

关 键 词:meso-四(2-羟基-5-磺酸苯基)卟啉  酸碱平衡

Synthesis of meso-Tetra(2-hydrox-5-sulphophenyl)porphyrin and Study on Its Acid-Base Equilibrium
Chen Xiuhua Tang Fulong Yang Xuemei. Synthesis of meso-Tetra(2-hydrox-5-sulphophenyl)porphyrin and Study on Its Acid-Base Equilibrium[J]. Chinese Journal of Analytical Chemistry, 1991, 19(4): 427-429
Authors:Chen Xiuhua Tang Fulong Yang Xuemei
Abstract:The method for synthesis of meso-tetra (2-hydrox-5-sulphophenyl) porphyrin [T(2-H-5-SP)P] and its acid-base equilibrium in aqueous solution have been studied.The ionization constants of T(2-H-5-SP)p were determined by using spectrophotometric method in aqueous solution.The pKa_1,pKa_2,pKa_3 and pKa_4 are 2.99,4.21,8.68 and 10.28 respectively.
Keywords:meso-Tetra(2-hydrox-5-sulphophenyl)porphyrin  Acid-base equilibrium
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