| Synthesis and Structure of Ru (pap)_2Cl_2 · 4EtOH |
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| 作者姓名： | Zhao Wei-Jun Zhang Shu-Ji Deng Yi Zhang Zheng-Zhi Ma Yan-Feng Huang Wei-Ping Wang Hong-Gen |
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| 作者单位： | Zhao Wei-Jun;Zhang Shu-Ji;Deng Yi;Zhang Zheng-Zhi;Ma Yan-Feng;Huang Wei-Ping;Wang Hong-Gen(Department of Chemistry，Institute of Elemento-Organic Chemisty，and Central Laboratory，Nankai University，Tianjin 300071，China |
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| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＳｔｒｕｃｔｕｒｅｏｆＲｕ（ｐａｐ）_２Ｃｌ_２·４ＥｔＯＨ￥ＺｈａｏＷｅｉ－Ｊｕｎ；ＺｈａｎｇＳｈｕ－Ｊｉ；ＤｅｎｇＹｉ；ＺｈａｎｇＺｈｅｎｇ－Ｚｈｉ；ＭａＹａｎ－Ｆｅｎｇ；ＨｕａｎｇＷｅｉ－Ｐｉｎｇ；ＷａｎｇＨｏｎｇ－Ｇｅｎ...
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Synthesis and Structure of Ru (pap)_2Cl_2 · 4EtOH |
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| Zhao Wei-Jun,Zhang Shu-Ji,Deng Yi,Zhang Zheng-Zhi,Ma Yan-Feng,Huang Wei-Ping,Wang Hong-Gen.Synthesis and Structure of Ru (pap)_2Cl_2 · 4EtOH[J].Chinese Journal of Structural Chemistry,1996(1). |
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| Authors: | Zhao Wei-Jun Zhang Shu-Ji Deng Yi Zhang Zheng-Zhi Ma Yan-Feng Huang Wei-Ping Wang Hong-Gen |
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| Abstract: | The reaction of Ru (DMSO)_4Cl_2 with Dipheny1-(pyrid-2-y1 ) amino]phosphine (pap) (1:2) gives the title compound Ru(PAP)_2Cl_2· 4EtoH. The crystallographic data for C_(24)H_(54)C_(12)N_4O_4P_2Ru: monoclinic,space group C2/c .α= 20. 47 (1) . b = 15. 431(9), c=15. 958(8) A , β=16. 82(4)°, V=4509(9) A3￣, Z=4, M_r= 912. 85, D_c= 1. 35 g/cm￣3,μ(MoKα) = 5. 71 cm￣(-1), F(000) =1092, R= 0. 073 and R_w = 0. 081 for 1700 observed reflections. The Ru atom is coordinated by two P atoms, two N atoms and two Cl atoms, forming octahedral coordination geomery. |
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| Keywords: | crystal structure synthesis phosphine Ru complex |
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