Kinetics of the N2O-CO reaction on Rh(1 1 0) |
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Authors: | Vladimir P. Zhdanov Osamu Nakagoe |
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Affiliation: | a Catalysis Research Center, Hokkaido University, Sapporo 001-0021, Japan b Boreskov Institute of Catalysis, Russian Academy of Sciences, Novosibirsk 630090, Russia |
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Abstract: | Our recent studies of the steady-state kinetics of the N2O-CO reaction on Rh(1 1 0) indicate that at CO excess, the reaction rate increases with increasing temperature. At N2O excess, the reaction rate is nearly independent of temperature at T < 520 K and rapidly decreases with increasing temperature at T > 520 K. Our present analysis of the relevant data indicates that the latter feature seems to be related to surface-oxide formation. Following this line, we propose a mean-field kinetic model making it possible to describe and clarify the experiment. |
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Keywords: | Heterogeneous catalysis Reaction kinetics Low index single crystal surfaces Rh(1 1 0) N2O CO N2 Oxygen |
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