Efficient generation of stable adducts of Si(II) dihydride using a donor-acceptor approach |
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| Authors: | Al-Rafia S M Ibrahim Malcolm Adam C McDonald Robert Ferguson Michael J Rivard Eric |
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| Institution: | Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada T6G 2G2. |
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| Abstract: | A stable Si(II) dihydride complex, IPr·SiH(2)·BH(3) (IPr = (HCNDipp)(2)C:]; Dipp = 2,6-(i)Pr(2)C(6)H(3)), was synthesized and preliminary reactivity involving this source of encapsulated silylene is reported. |
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