1,3-Bis[tert-butyl(di-tert-butylfluorsilyl)amino]trisulfan – eine Verbindung mit FSiNSSSNSiF-Helix |
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| Authors: | Uwe Klingebiel Frank Pauer George M. Sheldrick Dietmar Stalke |
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| Affiliation: | Institut für Anorganische Chemie der Universität Göttingen, Tammannstraße 4, W-3400 Göttingen |
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| Abstract: | 1,3-Bis[tert-butyl(di-tert-butylfluorosilyl)amino]trisulfane – a Compound with FSiNSSSNSiF Helix The lithium derivative of tert-butyl(di-tert-butylfluorosilyl)-amine ( 1 ) reacts with sulfur or selenium to give the bis[(fluorosilyl)-amino]di- and -trisulfanes 2, 3 and -selane 4 , respectively. The trisulfane 3 crystallizes from n-hexane and exhibits a helical structure (X-ray analysis). |
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| Keywords: | Disulfane, bis[(fluorosilyl)amino] derivative Trisulfane, 1,3-bis[(fluorosilyl)amino] derivative Selane, bis[(fluorosilyl)amino] derivative Helix structure |
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