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Diffusion controlled growth of hydrogen clusters in metals
Authors:B. Nowakowski  H. L. Frisch  Carlos Borzi  Ana Mijovilovich
Affiliation:1. Department of Chemistry, State University of New York at Albany, Albany, NY 12222 USA

On leave from Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PL-01-224 Warsaw, Poland.;2. Department of Chemistry, State University of New York at Albany, Albany, NY 12222 USA;3. Comision Nacional de Energia Atomica – GAID, Av. Libertador 8250 (1429) Buenos Aires, Argentina

Abstract:We show that a simple diffusion controlled growth, with subsequent aggregation, mean field theory accounts numerically for the growth of hydrogen clusters in certain metals (e.g. V, Nb, Zr, etc.). We also calculate the percolation threshold for the formation of an “infinite” aggregate both analytically and by a Monte Carlo simulation in a cubic lattice. The results are comparable and seem to correspond to the observed physical behavior.
Keywords:Hydrogen in metals  Hydrogen-clusters
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