Highly efficient oxidation of alcohols using Oxone~ as oxidant catalyzed by ruthenium complex under mild reaction conditions |
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作者单位: | Zi Qiang Lei~* Jian Qiang Wang Peng Hua Yan Key Laboratory of Polymer Materials of Gansu Province,College of Chemistry and Chemical Engineering,Northwest Normal University,Lanzhou 730070,China |
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摘 要: | Aromatic and alkyl alcohols were oxidized to the corresponding aldehydes or ketones at room temperature with high conversion and selectivity using Oxone(?)(2KHSO_5·KHSO_4·K_2SO_4)as oxidant catalyzed by ruthenium complex Quin-Ru-Quin(where Quin = 8-hydroxyquinoline).The reaction time is very short and the preparation of complex is simple.
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