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Nuclear magnetic resonance study of the smectic-cholesteric phase transition in a dimesogenic liquid crystal
Authors:Jun Hee Han  J.S. Kim  Jun Kue Park  Kyu Won Lee  J.-I. Jin  E.H. Choi  Cheol Eui Lee
Affiliation:1. Department of Physics, Korea University, Seoul 136-713, Republic of Korea;2. Department of Chemistry, Korea University, Seoul 136-713, Republic of Korea;3. Department of Electrophysics, Kwangwoon University, Seoul 130-701, Republic of Korea
Abstract:Nuclear magnetic resonance (NMR) spectroscopy has provided a unique opportunity to study the characteristic smectic-A to chiral nematic phase transition in a dimesogenic liquid crystal (“KI-5S”). The order parameters in the liquid crystalline phases were obtained from the 2H NMR quadrupole splitting and 13C NMR chemical shift measurements, manifesting a first-order smectic-nematic phase transition.
Keywords:Dimesogenic liquid crystal   Smectic to chiral nematic phase transition   Order parameters   Deuterium NMR and carbon NMR
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