Bis(dibenzo[c.e][1,2]oxaphosphorino)dichloroplatinum Complexes |
| |
| Authors: | György Keglevich Andrea Kerényi Helga Szelke Timea Imre |
| |
| Affiliation: | (1) Department of Organic Chemical Technology, Budapest University of Technology and Economics, 1521 Budapest, Hungary;(2) Research Group of the Hungarian Academy of Sciences, Department of Organic Chemical Technology, Budapest University of Technology and Economics, 1521 Budapest, Hungary;(3) Hungarian Academy of Sciences, Chemical Research Center, 1525 Budapest, Hungary |
| |
| Abstract: | Reaction of a series of P-amino and P-cycloalkoxy dibenzo[c.e][1,2]oxaphosphorines (1), (3) and (5) with cis-bis(benzonitrile)dichloroplatinum(II) afforded the title bis(dibenzooxaphosphorino) complexes (2), (4) and (6), respectively. In the case of chiral P-substituents, the complexes (4) and (6) were obtained in homo and heterochiral forms. Stereospecific 1J(195Pt–P) couplings found in the 31P-n.m.r. spectra of the products (2), (4) and (6) suggested the cis orientation of the identical substituents. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
