| 鱼贝类水产品中有机锡的气相色谱-脉冲火焰光度法测定研究 |
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| 引用本文： | 吕华东,傅武胜,林麒,蔡一新,赵云峰,陶学燕. 鱼贝类水产品中有机锡的气相色谱-脉冲火焰光度法测定研究[J]. 分析试验室, 2008, 27(10) |
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| 作者姓名： | 吕华东 傅武胜 林麒 蔡一新 赵云峰 陶学燕 |
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| 作者单位： | 福建省疾病预防控制中心,福州,350001;中国疾病预防控制中心营养与食品安全所,北京,100050 |
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| 基金项目： | 福建省科技攻关重点项目沿海鱼贝类有机锡化合物蓄积量及检测技术研究(2004Y015); 科技部重大专项《食品安全关键技术》重要有机污染物痕量与超痕量检测技术研究”课题 |
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| 摘 要： | 采用振荡萃取法,以凝胶渗透色谱净化浓缩液,用戊基溴化镁衍生;衍生物经弗罗里硅土净化后,用气相色谱-脉冲火焰光度法（GC-PFPD）测定,以内标法定量,建立了鱼贝类水产品中8种有机锡的分析方法。方法的线性范围在10-500μg/mL之间,检出限为1.0μg/kg左右。以牡蛎干粉为基质,在10和40μg/kg水平下加标,各有机锡的平均回收率在82.0%-104%之间,相对标准差（RSD）为1.4%-13.3%,牡蛎标准参考物测定结果落在定值范围内。
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| 关 键 词： | 有机锡 气相色谱 鱼贝类食品 |
Determination of multi-organotins in seafood products by gas chromatography coupled with pulsed flame photometric detection |
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| L Hua-dong,FU Wu-sheng,LIN Qi,CAI Yi-xin,ZHAO Yun-feng,TAO Xue-yan. Determination of multi-organotins in seafood products by gas chromatography coupled with pulsed flame photometric detection[J]. Chinese Journal of Analysis Laboratory, 2008, 27(10) |
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| Authors: | L Hua-dong FU Wu-sheng LIN Qi CAI Yi-xin ZHAO Yun-feng TAO Xue-yan |
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| Affiliation: | L(U) Hua-dong,FU Wu-sheng,LIN Qi,CAI Yi-xin,ZHAO Yun-feng,TAO Xue-yan |
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| Abstract: | A method for quantifying multi-organotins in seafoods was evaluated.The samples were extracted by shaking method and the extracts were concentrated under the reduced pressure.The residues were cleaned up with gel penetration chromatography(GPC).The concentrated eluent was derivatized with pentylmanesium bromide.The derivative products were cleaned up with florisil column and concentrated before injected into GC-PFPD.Monomethyltin(MMT) was used as internal standard for mono-substituent coumpouds,and tripropy... |
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| Keywords: | Organotins Gas chromatography Seafoods |
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