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Zirconium-phosphate-fluoride gels
Authors:E. Fakhari  T. Schönfeld
Affiliation:(1) Institute of Inorganic Chemistry, University of Vienna, A-1090 Wien, Austria
Abstract:Summary The volume of amorphous zirconium phosphate precipitates formed in acid solutions (pH=0–2) is increased many times by the action of fluoride (hydrofluoric acid). At fluoride concentrations corresponding to a maximum precipitate volume, the particles slowly (during several days) coalesce to form a semi-solid gel.Dedicated to Univ. Prof. Dr.O. Olaj, University of Vienna, on the occasion of his 60th birthday
Keywords:Fluoride ligands  Gels  Phosphate bridges  Polymeric zirconium cations  Zirconium phosphate  Zirconium-fluoride coordination
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