Zwei neue Oxopalladate: BaPdNd2O5 und BaPdSm2O5 mit planar koordinierten Pd2+-Ionen |
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| Authors: | Stephan Schiffler Hanskarl Müller-Buschbaum |
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| Affiliation: | 1. Institut für Anorganische Chemie, Christian-Albrechts-Universit?t Kiel, D-2300, Kiel, Bundesrepublik Deutschland
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| Abstract: | Single crystals of BaPdNd2O5 (A), BaPdSm2O5 (B) and BaCuNd2O5 (C) were prepared by solid state reaction using BaCl2 as a fusing assistant (A, B) or by high temperature Laser technique (C). X-ray investigations show tetragonal symmetry with A:a=6.7387 (5),c=5.9002 (25) Å, B:a=6.6667 (13),c=5.8800 (6) Å (space group D 4h 5 ?P4/mbm,Z=2). The formerly investigated compound (C) is refined here by single crystal data. (A) and (B) belong to the BaPtNd2O5-type. The results are discussed. |
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